Abstract: “Zero pollution” village is a scientific implementation plan of construction of ecological civilization and beautiful countryside, and an effective way to realize the goal of ecological livability. This study introduces participatory governance to the “zero pollution” village governance field, and takes D Village of Zhejiang Province, China as a typical case of “zero pollution” village governance, trying to explore the governance path and implementation mechanism of “zero pollution” villages. The study shows that the current path of participatory governance of “zero-pollution” villages is as follows: support is the foundation, the empowerment of the main body is the key, consultation and cooperation is the guarantee, and autonomy and sharing is the goal. On the above basis, Stoker’s Clear model can be used to refine the realization mechanism of “zero pollution” village participatory governance into the villagers’ “can do”, “like to do”, “enable to do”, “are asked to do” and “respond to do”, so as to improve the governance performance of “zero pollution” villages and ultimately achieve the goal of rural ecological livability.